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Most of the reactions proceeded in anti. Both hydrogen atoms come from h2o. In the borrowing hydrogen catalysis,.
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Cooperative bimetallic radical catalysis that enables asymmetric hat without the formation of carbon radicals. By selecting an appropriate phosphine, a more reactive olefin can be selectively hydrogenated. Herein, we report a new conceptual approach:
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Realizing efficient hydrogenation of n 2 molecules in the electrocatalytic nitrogen reduction reaction (nrr) is crucial in achieving high activity at a low potential because it.
Radical hydrogenation via hydrogen atom transfer (hat) to alkenes is an increasingly important transformation for the formation of thermodynamic alkane isomers. Hydrogenation at β position is the rate determining. Hydrometalation of alkenes with transition─metal hydrides(m─h) represents an important step in transition─metal─ catalyzed transformations.
